James Stewart Scoates
Relevant Degree Programs
Graduate Student Supervision
Doctoral Student Supervision (2008-2018)
Mafic layered intrusions in the Earth’s crust are natural laboratories for evaluating differentiation processes of mantle-derived magma. The Mesoproterozoic Kiglapait intrusion (Labrador, Canada) represents a remarkable case study of how these intrusions form under closed-system crystallization of basaltic magma. The Kiglapait intrusion is the largest and youngest troctolitic intrusion contained within the vast Nain Plutonic Suite, one of the best-preserved examples of Proterozoic anorthosite massifs that distinguish magmatic activity in the Earth’s crust from ~1.8 to 0.9 billion years ago. The radiogenic isotope ratios of Pb-Sr-Nd-Hf are powerful geochemical tools for identifying magma sources, detecting contamination, and tracing mixing processes in igneous rocks. To measure accurate and precise isotopic ratios by MC-ICP-MS, the analysis of sample–matrix-matched reference materials is required. A new comprehensive isotope database of mafic to ultramafic reference materials is provided to assess the accuracy of Pb-Sr-Nd-Hf isotopes in Kiglapait samples and to be used as a reference dataset for the isotopic study of other terrestrial, and extraterrestrial, mafic-ultramafic rocks. Integration of Pb-Sr-Nd-Hf isotope and trace element geochemistry of whole rocks and mineral separates allows for definition of the Kiglapait source and parent magma composition. An event of post-crystallization addition of radiogenic Pb is distinguished, the effects of which are effectively leached from plagioclase during sample pre-treatment. An in situ LA-ICP-MS technique is also developed for measuring Pb isotope ratios at high spatial resolution in minerals with very low Pb concentrations, such as plagioclase and clinopyroxene. Combined, the solution-based Pb-Sr-Nd-Hf and in situ Pb isotopic results demonstrate that the primary Kiglapait magma was mantle-derived, with minor assimilation of lower crust during ponding and ascent, and that assimilation of local country rocks, as recorded primarily in Sr isotopic variations, was limited to the uppermost gabbros and ferrosyenites during the final stages of crystallization. This multi-isotopic and trace element geochemical framework developed for the Kiglapait intrusion, and at a larger scale for the entire Nain Plutonic Suite, can be adapted to layered intrusions and Proterozoic anorthosite plutonic suites worldwide to better constrain a wide range of geological issues from mantle heterogeneity to crustal differentiation to Proterozoic geodynamics.
The Neoarchean Stillwater Complex (Montana, USA) and the Paleoproterozoic Bushveld Complex (South Africa), two of the world’s largest layered intrusions, have been cornerstones for the study of magmatic processes in the Earth’s crust. Mafic layered intrusions are natural laboratories for assessing the emplacement, crystallization, and cooling mechanisms of mantle-derived basaltic magmas. Most layered intrusions do not yet have robust geochronological frameworks from the base to the top of their stratigraphic successions. Zircon is recognized as a relatively common accessory mineral in the Stillwater and Bushveld intrusions and crystallized from highly fractionated interstitial melt at near-solidus temperatures (980-720°C). High-precision geochronologic frameworks established for both intrusions by U-Pb zircon dating, combined with trace element and hafnium isotope compositions of zircon, reveal extended durations of magmatism (3-5 million years) and non-stratigraphic or out-of-sequence ages for both intrusions. Dating of platinum group element deposits in both intrusions (J-M Reef, Stillwater; Merensky Reef, Bushveld) indicates that they are intrusion-wide time markers that crystallized synchronously over large distances (>300 km, Bushveld). The recognition that zircon can be successfully extracted from mafic-ultramafic rocks associated with magmatic ore deposits provides new opportunities for assessing the timing and duration of mineralization processes in layered intrusions worldwide. Zircon from a thick anorthosite horizon in the Stillwater Complex has been identified as a reference material for U-Pb geochronology of Archean rocks (>2.5 Ga) and fills an important gap in the geologic timescale for the application of precise and accurate U-Pb geochronology. Collectively, the dating results indicate that both the Stillwater Complex and Bushveld Complex do not represent the products of progressively crystallized magma chambers but instead formed as stacks of amalgamated sills representing repeated injections of magma at different stratigraphic levels. These conclusions call into question current concepts regarding the origin of layered intrusions and challenge us to rethink our understanding of the timescales of magma processes throughout Earth history.
The isotopic compositions of oceanic island basalts erupted at the Earth’s surface can be used to directly constrain the isotopic signatures of their deep mantle sources. Basaltic rocks are highly susceptible to seawater alteration, which can significantly modify elemental contents and potentially hinder the use of radiogenic isotopes as geochemical tracers. In this study, multi-isotopic (e.g., Pb-Hf-Sr-Nd) analyses on the same acid-leached sample aliquot are shown to produce reliable results for use in the discrimination of mantle source components of oceanic basalts. Application to basalts from the Ninetyeast Ridge in the Indian Ocean and from Mauna Kea volcano on Hawaii in the Pacific Ocean allows for an enhanced resolution of their source components and distribution in the deep mantle. Isotopic geochemistry of the Ninetyeast Ridge sampled during Ocean Drilling Project Leg 121 reveals a Kerguelen and Amsterdam-St. Paul mantle plume origin with the presence of at least three source components and no contribution from an Indian mid-ocean ridge basalt source. The isotopic characteristics of the Ninetyeast Ridge basalts are typical of the Dupal isotopic domain and consistent with recycling of altered oceanic crust and a mixture of pelagic sediments and lower continental crust into their mantle source. This supports a deep origin for the enriched mantle “EM-1”-like Dupal signatures encountered in Indian Ocean island basalts. In the Pacific Ocean, isotopic heterogeneity in basalts from the deepest parts of the Hawai’i Scientific Drilling Project (HSDP2) core on Mauna Kea, combined with prior results from overlying flows, indicate that shield basalts can be explained by mixing of variable proportions of four isotopically distinct components intrinsic to the Hawaiian mantle plume. The “Kea” component is the prevailing composition in Mauna Kea basalts and throughout volcanic activity of the Hawaiian hotspot. The relatively depleted isotopic compositions of this “Kea” component are shared by other Pacific oceanic island basalt groups and are very similar to those of the common mantle component “C”. This suggests that “Kea” may be a common and widespread composition within the deep mantle beneath the Pacific Ocean basin.
The Saint-Urbain and Big Island rutile-bearing ilmenite Fe-Ti oxide deposits are locatedin the composite 450 km² Saint-Urbain anorthosite (1055-1046 Ma, U-Pb zircon) and inthe Lac Allard intrusion (1057-1062 Ma, U-Pb zircon) of the 11,000 km² Havre-SaintPierre anorthosite suite, respectively, in the Grenville Province of Eastern Canada. Slowcooling rates of 3-4°C/m.y. are estimated for both anorthosites, based on combined U-Pbzircon/rutile/apatite and ⁴⁰Ar/³⁹ Ar biotite/plagioclase geochronology, and resulted fromemplacement during the active Ottawan Orogeny. Slow cooling facilitated (1) diffusionof Zr from ilmenite and rutile, producing thin (10-100 microns) zircon rims on theseminerals, and (2) formation of sapphirine via sub-so lidus reactions of the type: spinel +orthopyroxene + rutile ± corundum → sapphirine + ilmenite. New chemical andanalytical methods were developed to determine the trace element concentrations and Hfisotopic compositions of Ti-based oxides. Rutile is a magmatic phase in the depositswith minimum crystallization temperatures of 781°C to 1016°C, calculated by Zr-inrutile thermometry. Ilmenite present in rutile-free samples has higher Xhem (hematiteproportion in ilmenite), higher high field strength element concentrations (Xhem = 30-17;Nb = 16.1-30.5 ppm; Ta 1.28-1.70 ppm), and crystallized at higher temperatures thanilmenite with more fractionated compositions (Xhem = 21-11; Nb = 1.36-3.11 ppm; Ta =
The Wrangellia flood basalts are parts of an oceanic plateau that formed in theeastern Panthalassic Ocean (ca. 230-225 Ma). The volcanic stratigraphy presently extends>2300 km in British Columbia, Yukon, and Alaska. The field relationships, age, andgeochemistry have been examined to provide constraints on the construction of oceanicplateaus, duration of volcanism, source of magmas, and the conditions of melting andmagmatic evolution for the volcanic stratigraphy.Wrangellia basalts on Vancouver Island (Karmutsen Formation) form anemergent sequence consisting of basal sills, submarine flows (>3 km), pillow breccia andhyaloclastite (1.5 km). Karmutsen stratigraphy overliesDevonian to Permian volcanic arc (~380-355 Ma) and sedimentary sequences and isoverlain by Late Triassic limestone. The Karmutsen basalts are predominantlyhomogeneous tholeiitic basalt (6-8 wt% MgO); however, the submarine part of thestratigraphy, on northern Vancouver Island, contains picritic pillow basalts (9-20 wt%MgO). Both lava groups have overlapping initial EHf and ENd, indicating a common, oceanisland basalt (OIB)-type Pacific mantle source similar to the source of basalts from theOntong Java and Caribbean Plateaus. The major-element chemistry of picrites indicatesextensive melting (23-27%) of anomalously hot mantle (~1500°C), which is consistentwith an origin from a mantle plume head.Wrangellia basalts extend ~450 km across southern Alaska (Wrangell Mountainsand Alaska Range) and through southwest Yukon where
Master's Student Supervision (2010-2017)
The Early Jurassic (>188-185 Ma) Turnagain ultramafic-mafic body, a composite Alaskan-type intrusion in the Northern Cordillera of northern British Columbia, hosts a significant nickel-cobalt resource (Horsetrail zone, 1842 Mt @ 0.21 wt. % Ni and 0.013 wt. % Co), and minor copper-platinum group element (Cu-PGE) mineralization. The 24 km² Turnagain intrusion comprises four temporally, spatially, and chemically distinct ultramafic-mafic phases that include dunite, wehrlite, clinopyroxenite, hornblendite and diorite. The 1.5 x 2 km DJ/DB zone, an area of Cu-PGE enrichment that was discovered through soil geochemistry and drilling of a previously under-explored area of the intrusion, is located 2.5 km northwest of the nickel resource. Clinopyroxenites and hornblendites with minor wehrlite are the major rock types of the DJ/DB zone. Orthomagmatic sulphide mineralization ranges from predominantly disseminated sulphides (
The Giant Mascot Ni-Cu-PGE deposit remains British Columbia’s only past-producing nickel mine (1958-1974) with ~4.2 Mt of ore grading 0.77% Ni, 0.34% Cu, minor Co, Ag, and Au, and unreported platinum group elements (PGE). The deposit is part of a new class of ‘convergent margin’ Ni-Cu-PGE sulphide deposits containing orthopyroxene and magmatic hornblende. The ultramafic-mafic intrusions that host these deposits have relatively small footprints, generally less than ~10 km2 (e.g., Portneuf-Mauricie Domain, Québec; Huangshandong, China; Aguablanca, Spain), and they are becoming increasingly important economic resources globally. Zircon was successfully separated from feldspathic ultramafic rocks and yield a weighted ²⁰⁶Pb/²³⁸U age of crystallization for the Giant Mascot ultramafic intrusion of ca. 93 Ma (CA-TIMS, n=8), thus constraining the age of mineralization and distinguishing it as one of the world’s youngest Ni deposits. The Giant Mascot intrusion is a crudely elliptical, 4×3 km plug composed of ultramafic arc cumulates (olivine-orthopyroxene, hornblende-clinopyroxene) that intruded the Late Cretaceous Spuzzum pluton. Sub-vertical pipe-like, lensoid and tabular bodies (n=28) host orthomagmatic Ni-Cu-PGE mineralization as disseminated, net-textured, semi-massive, and massive ores consisting of pyrrhotite, pentlandite, chalcopyrite, minor pyrite, troilite, and Pt-Pd-Ni bismuthotellurides. The sulphides have high tenors (3-14 wt% Ni, 0.1-17.1 wt% Cu, 84 ppb-5 ppm total PGE) and distinct iridium-group PGE concentrations that represent varying stages of monosulphide solid solution fractionation and subsequent metal enrichment of two magma types forming the Western and Eastern mineralized zones. Sulphur isotopes (n=34) for sulphides in ultramafic rocks reveal δ³⁴S values (-3.4 to -1.3‰) lighter than typical mantle values and overlap with analyses from locally pyritiferous Settler schist (-5.4 to -1.2‰). Sulphide saturation in the Giant Mascot parental magma(s) was triggered in response to 1) reduction of an oxidized, mantle-derived arc magma, 2) addition of external sulphur and silica by assimilation of Settler schist and Spuzzum diorites, and 4) fractional crystallization. The presence of high-tenor sulphides indicates that orogenic Ni-Cu-PGE deposits may be of greater significance to future exploration globally than previously assumed.